Journal
ORGANIC LETTERS
Volume 13, Issue 8, Pages 2110-2113Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200465z
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Funding
- Chinese National Natural Science Foundation [20732004, 20972130]
- key project of Tianjin [TJAB-2009-023]
- Key Scientific Project of Fujian Province [2009HZ0004-1]
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A mild and efficient method was developed for the copper-catalyzed additions of H-phosphonate diesters to boronic acids under the copper catalyst system Cu2O/1,10-phenanthroline. To the best of our knowledge this finding is the first example of a copper-catalyzed synthesis of aryl phosphonates from arylboronic acids and H-phosphonate dialkyl esters.
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