Journal
ORGANIC LETTERS
Volume 13, Issue 6, Pages 1429-1431Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol103143a
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Funding
- MEXT [21656033]
- Mitsubishi Chemical Corporation Fund
- Sumitomo Foundation
- Astellas Award in Synthetic Organic Chemistry, Japan
- Grants-in-Aid for Scientific Research [21656033] Funding Source: KAKEN
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1,2,3-Benzotriazin-4(3H)-ones and 1,2,3,4-benzothiatriazine 1,1(2H)-dioxide reacted with isocyanides in the presence of a palladium catalyst to give 3-(imino)isoindolin-1-ones and 3-(Imino)thiaisoindoline 1,1-dioxides, respectively, In high yield. An intermediate azapalladacycie was generated through denitrogenation of the triazine moiety, and an isocyanide was Incorporated therein.
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