Journal
ORGANIC LETTERS
Volume 13, Issue 2, Pages 276-279Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102688e
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Funding
- NSFC [20672006, 20821062, 20832002, 20925207, GZ419]
- MOST of China [2009CB825300]
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The most efficient method to construct biaryls is the direct dehydrogenative cross-coupling of two different aromatic rings. Such an ideal cross arylation starting from distinct polyfluoroarenes and simple arenes was presented. The selectivity of the cross-coupling was controlled by both of the electronic property of fluoroarenes and steric hindrance of simple arenes. Diisopropyl sulfide was essential to promote the efficacy.
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