Journal
ORGANIC LETTERS
Volume 13, Issue 19, Pages 4977-4979Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202081c
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- Canada Research Chair (Tier I) Foundation
- CFI
- NSERC
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A novel, direct para-selective oxidative cross-coupling of benzene derivatives with cycloalkanes catalyzed by ruthenium was developed. A wide range of arenes bearing electron-withdrawing substituents was functionalized directly with simple cycloalkanes with high para-selectivity; arenes with electron-donating groups were mainly para-functionalized. Benzoic acid can be used directly.
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