Journal
ORGANIC LETTERS
Volume 13, Issue 9, Pages 2188-2191Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200407r
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Funding
- National Institutes of Health [NIH GM-082935]
- National Science Foundation [NSF-0847108]
- NIH/NHLBI [1K22HL088341-01A1]
- University of South Florida
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0847108] Funding Source: National Science Foundation
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Conditions for a catalytic asymmetric aza-Darzens aziridine synthesis mediated by a vaulted biphenanthrol (VAPOL) magnesium phosphate salt is described. Using simple substrates, this methodology explores the scope and reactivity of a new magnesium catalyst for an aziridination reaction capable of building chirality and complexity simultaneously.
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