4.8 Article

Development of Mono- and Di-AcO Substituted BODIPYs on the Boron Center

Journal

ORGANIC LETTERS
Volume 14, Issue 1, Pages 248-251

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol2030229

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Funding

  1. National Natural Science Foundation of China [20872026]
  2. Hi-Tech Research and Development Program of China (863 Plan) [2009AA02Z308]
  3. Shanghai Pujiang Talent Plan Project [09PJD008]
  4. Sino Swiss Science and Technology Cooperation (SSSTC) [EG 30-032010]

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Mono- and di-AcO substituted BODIPYs (1 and 2) were synthesized from TM-BDP. The structures of 1 and 2 were supported by single crystal X-ray analysis. Both 1 and 2 possess a large absorption coefficient, high fluorescence quantum yield, and high light stability. Compound 2 has much Improved water solubility which is highly desirable for biological applications. Theoretical calculation supports our observations In X-ray analysis, absorption, and cyclic voltammetry.

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