Journal
ORGANIC LETTERS
Volume 13, Issue 5, Pages 948-951Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102994q
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- Netherlands Organization for Scientific Research (NWO-CW)
- China Scholarship Council [2008618001]
- Spanish Ministry of Science and Innovation (MICINN)
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An efficient catalytic asymmetric synthesis of chiral gamma-butenolides was developed based on the hetero-allylic asymmetric alkylation (h-AAA) in combination with ring closing metathesis (RCM). The synthetic potential of the h-AAA-RCM protocol was illustrated with the facile synthesis of (-)-whiskey lactone, (-)-cognac lactone, (-)-nephrosteranic acid, and (-)-roccellaric acid.
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