4.8 Article

1,1-Carboboration of 1-Alkynes: A Conceptual Alternative to the Hydroboration Reaction

Journal

ORGANIC LETTERS
Volume 13, Issue 1, Pages 62-65

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol102544x

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Funding

  1. Deutsche Forschungsgemeinschaft
  2. Alexander von Humboldt-Stiftung

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Strongly electrophilic boranes R-B(C6F5)(2) react readily with a variety of 1-alkynes by means of a 1,1-carboboration reaction to yield alkenylborane products, which can subsequently be used as reagents in metal catalyzed cross-coupling reactions.

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