4.8 Article

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C-H Activation

Journal

ORGANIC LETTERS
Volume 13, Issue 3, Pages 540-542

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol102890k

Keywords

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Funding

  1. NIH [GM069559]
  2. Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division, U.S. Department of Energy [DE-AC02-05CH11231]
  3. Eli Lilly Fellowship
  4. European Community

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Oxime directed aromatic C-H bond activation and oxidative coupling to alkenes is reported using a cationic Rh(III) catalyst. Significantly, the method can be used to oxidatively couple unactivated, aliphatic alkenes.

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