Journal
ORGANIC LETTERS
Volume 14, Issue 1, Pages 18-21Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202641y
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Funding
- National High Technology Projects 863 [2008AA022317]
- Program for New Century Excellent Talents in University [NCET-10-0614]
- NSFC [20802050, 21072150]
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An efficient method using silver oxide-mediated oxidation for the synthesis of ortho-quinone methides has been developed and applied to the biomimetic syntheses of novel trimeric natural products, (+/-)-schefflone and tocopherol trimers. Further studies of the critical trimerization as well as substrate scope and limitations are also reported.
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