4.8 Article

Perylene Anhydride Fused Porphyrins as Near-Infrared Sensitizers for Dye-Sensitized Solar Cells

Journal

ORGANIC LETTERS
Volume 13, Issue 14, Pages 3652-3655

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol201303h

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Funding

  1. Singapore DSTA DIRP [DSTA-NUS-DIRP/2008/03]
  2. NRF [R-143-000-360-281]
  3. NUS [R-143-000-356-101]
  4. A*Star BMRC-NMRC [10/1/21/19/642]
  5. IMRE [IMRE/10-1P0509]
  6. KAUST

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Two perylene anhydride fused porphyrins 1 and 2 have been synthesized and employed successfully in dye-sensitized solar cells (DSCs). Both compounds showed broad incident monochromatic photon-to-current conversion efficiency spectra covering the entire visible spectral region and even extending into the near-Infrared (NIR) region up to 1000 nm, which is impressive for ruthenium-tree dyes in DSCs.

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