4.8 Article

Ni-Catalyzed Intramolecular Cycloaddition of Methylenecyclopropanes to Alkynes

Journal

ORGANIC LETTERS
Volume 13, Issue 4, Pages 640-643

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol1028628

Keywords

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Funding

  1. Natural Science Foundation of China [21072169, 20872126]
  2. Fundamental Research Funds for the Central Universities [2010QNA3011]

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Ni-catalyzed intramolecular cycloaddition of methylenecyclopropanes (MCPs) to arkylalkynes via proximal bond cleavage is reported. The reaction provides a facile route for the preparation of cyclopenta[a]indene derivatives.

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