Journal
ORGANIC LETTERS
Volume 13, Issue 18, Pages 4818-4821Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2018938
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Funding
- National Natural Science Foundation of China [20834004, 91027006]
- Fundamental Research Funds for the Central Universities [2010QNA3008]
- National Basic Research Program [2009CB930104]
- Zhejiang Provincial Natural Science Foundation of China [R4100009]
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Two new copillar[5]arenes were prepared. They are arranged in two completely different motifs, a cyclic dimer containing two monomers with two different conformations that are mirror images of each other and linear supramolecular polymers in the solid state. Not only has it been shown that to form this kind of dimer is a unique feature associated with pillar[5]arene macrocycles but also it was demonstrated that weak van der Weals forces can be used to control the self-organization of monomers during their supramolecular polymerization process.
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