Journal
ORGANIC LETTERS
Volume 13, Issue 9, Pages 2278-2281Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2005424
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Funding
- KAKENHI [19750075]
- Grants-in-Aid for Scientific Research [22550098, 19750075] Funding Source: KAKEN
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A new catalytic system for the dehydrogenative oxidation of alcohols using a Cp*Ir complex having a functional C,N-chelate ligand has been developed. With this catalytic system, both primary and secondary alcohols were efficiently converted to aldehydes and ketones, respectively. Mechanistic investigations of this catalytic system have revealed that the catalytically active species is a hydrido iridium complex with a functional C,N-chelate ligand.
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