Journal
ORGANIC LETTERS
Volume 13, Issue 22, Pages 5940-5943Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202603e
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Funding
- 973 Program [2009CB825300]
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A novel, efficient, and highly regloselective Lewis acid-catalyzed [3 + 2] cycloaddition of alkynes with azomethine ylides, which are easily obtained from N-tosylaziridines via C-C bond heterolysis at room temperature was developed. Moderate enantioselectivity (70% ee) can be achieved by the application of the commercially available chiral Pybox 7 as the ligand.
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