4.8 Article

Utilization of Natural Sunlight and Air in the Aerobic Oxidation of Benzyl Halides

Journal

ORGANIC LETTERS
Volume 13, Issue 9, Pages 2168-2171

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol2002013

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Funding

  1. Peking University
  2. National Science Foundation of China [20702002, 20872003]
  3. 973 Program [2009CB825300]

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A novel, efficient oxidation of alpha-aryl halogen derivatives to the corresponding alpha-aryl carbonyl compounds at room temperature has been disclosed. Natural sunlight and air are successfully utilized in this approach through the combination of photocatalysis and organocatalysis. A plausible mechanism was proposed on the basis of the mechanistic studies.

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