Journal
ORGANIC LETTERS
Volume 13, Issue 7, Pages 1840-1843Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200352g
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A general and facile one-pot procedure for the synthesis of 2-substituted pyridines from the corresponding pyridine-N-oxides and nucleophiles is presented as a mild alternative to SNAr chemistry. A variety of nucleophiles and heterocyclic-N-oxides participate effectively in this transformation, which uses the phosphonium salt, PyBroP, as a means of substrate activation.
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