4.8 Article

Perylene-Fused BODIPY Dye with Near-IR Absorption/Emission and High Photostability

Journal

ORGANIC LETTERS
Volume 13, Issue 4, Pages 632-635

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol102879g

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Funding

  1. Singapore DSTA [DSTA-NUS-DIRP/2008/03]
  2. NRF [R-143-000-360-281]
  3. NUS [R-143-000-356-101]
  4. KAUST

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A N-annulated perylene unit was successfully fused to the meso- and beta-positions of a boron dipyrromethene (BODIPY) core. The newly synthesized BODIPY dye 1b exhibits intensified near-Infrared (NIR) absorption and the longest emission maximum ever observed for all BODIPY derivatives. In addition, this dye possesses excellent solubility and photostability, beneficial to practical applications.

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