Journal
ORGANIC LETTERS
Volume 13, Issue 4, Pages 706-708Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102942w
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- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [22550101] Funding Source: KAKEN
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The ruthenium-catalyzed oxidative vinylation of thiophene-2-carboxylic acids with alkenes efficiently proceeds through directed C-H bond cleavage to give the corresponding 3-vinylated products. Similarly, benzothiophene-, benzofuran-, pyrrole-, and indolecarboxylic acids also undergo regioselective vinylation.
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