Journal
ORGANIC LETTERS
Volume 13, Issue 12, Pages 3182-3185Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200841x
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Funding
- European Research Council under the European Community [FP7/2007-2013]
- ERC [227763]
- Alexander von Humboldt Foundation
- European Research Council (ERC) [227763] Funding Source: European Research Council (ERC)
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Sulfoxide-alkene hybrids are introduced as a new class of chiral heterodentate ligands for the Hayashi-Miyaura reaction. The synthesis of these ligands was achieved without the use of protecting groups. A chiral resolution was performed via simple column-chromatographic separation of the diastereomeric ligands. Both diastereomers proved to be excellent ligands In Rh-catalyzed 1,4-addition reactions, furnishing chiral Products with high enantloselectivities and, remarkably, opposite stereoconfigurations.
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