Journal
ORGANIC LETTERS
Volume 13, Issue 13, Pages 3399-3401Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol201144w
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Funding
- DFG [SPP1355]
- One-P large-scale Project [212311]
- BASF SE
- IMPRS
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Via one-step copper catalyzed procedures it was possible to synthesize 2,5,8,11-tetrabromo, tetrachloro, and tetracyano derivatives of perylenediimides. Characterization of optical and electrochemical properties of these materials proves substantial enhancement of the electron affinity, with a LUMO level as low as -4.4 eV in the case of the tetracyano perylenediimide.
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