Journal
ORGANIC LETTERS
Volume 13, Issue 17, Pages 4680-4683Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol201898x
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Funding
- MOST [2009CB82530]
- Ministry of Education
- NSFC [20732006, 21002083]
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The first catalytic asymmetric 1,3-dipolar cycloaddition of electron-deficient carbon carbon triple bonds with azomethine ylides has been established. This reaction provides an unprecedented approach to access novel 2,5-dihydropyrrole derivatives with potential bloactivities in perfect enantioselectivities of up to > 99% ee.
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