Journal
ORGANIC LETTERS
Volume 14, Issue 1, Pages 234-237Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2030179
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Funding
- NSF
- NIH [GM 033049]
- W.S. Johnson Graduate Fellowship
- Bing Summer Fellowship
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0846427] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1145236] Funding Source: National Science Foundation
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Nitroalkenes readily undergo palladium-catalyzed [3 + 2] cycloaddition with trimethylenemethane to generate nitrocyclopentanes In excellent yield and enantioselectivity. Furthermore, the products thus formed are highly versatile synthetic intermediates and provide convenient access to both cyclopentylamines and cyclopentenones.
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