Journal
ORGANIC LETTERS
Volume 13, Issue 16, Pages 4348-4351Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol201679f
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Funding
- National Natural Science Foundation of China [20973178]
- National Basic Research Program of China (973 Program) [2010CB833300]
- Chinese Academy of Sciences
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A range of cyclic N-alkyl imines were efficiently hydrogenated by using a chiral cationic Ru(eta(6)-cymene)(MsDPEN)(BArF) complex (MsDPEN = N-(methanesulfonyl)-1,2-diphenylethylenediamine) In high yields and up to 98% ee. A one-pot synthesis of chiral 2-phenylpyrrolidine via reductive amination was also developed.
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