Journal
ORGANIC LETTERS
Volume 13, Issue 8, Pages 1916-1919Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200189y
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- CNRS
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Phenyliodine(III) bis(trifluoroacetate) (PIFA) in conjunction with a Lewis acid promotes C-C coupling of Bodipy monomers leading to mixtures of various oligomers. When a single position is blocked with an iodo or phenyl group, formation of the dimer is favored. These dimers display two successive oxidation and two reduction waves separated on average by 260 and 130 mV, respectively, corresponding to each Bodipy subunit.
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