Journal
ORGANIC LETTERS
Volume 13, Issue 7, Pages 1718-1721Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200231z
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [22106514] Funding Source: KAKEN
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Reactions of thioamide dianions, derived from secondary N-arylmethyl thioamides using Bat, with thioformamides followed by the addition of iodine to yield 5-amino-2-thiazolines are described. Treatment of the 5-amino-2-thiazolines with iodine leads to a highly efficient production of 5-aminothiazoles. When N,N-diarylthioformamides are employed in this process, fluorescent 5-N,N-diarylthiazoles are obtained.
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