Journal
ORGANIC LETTERS
Volume 13, Issue 15, Pages 3767-3769Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol201320v
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Funding
- National Science Foundation [CHE-1057350]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1057350] Funding Source: National Science Foundation
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An efficient synthesis of (+/-)-minfiensine has been accomplished employing an intramolecular Diels-Alder cycloaddition/rearrangement cascade of an amidofuran derivative. Thermal reorganization of the Initially formed [4 + 2]-cycloadduct affords the critical tetrahydroiminoethanocarbazole skeleton of the alkaloid in high yield.
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