Journal
ORGANIC LETTERS
Volume 13, Issue 21, Pages 5754-5757Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202329s
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Funding
- University of California, Davis
- American Chemical Society
- NIH/NIGMS [P41-GM0089153]
- 3M Nontenured faculty
- United States Department of Education
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The indium(III)-catalyzed enantioselective and regioselective addition of pyrroles to isatins is described. The effects of metal and solvent on the reactivity and selectivity are compared and discussed, demonstrating that the indium(III)-indapybox complex provides the most effective catalyst. A case of divergent reactivity between pyrroles and indoles is presented.
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