Journal
ORGANIC LETTERS
Volume 13, Issue 4, Pages 724-727Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102955e
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Funding
- NSFC [20621091, 20672048, 20732002, 20972059]
- MOE [2010CB833200]
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A TiCl4-promoted tandem intramolecular Prins cyclization/Schmkit reaction has been designed and developed to be an efficient method for the construction of the azaspiro[4,4]nonane. The present tandem protocol has been employed to construct the tricyclic azaquaternary skeleton (ring A, B, and C) of stemonamine.
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