Journal
ORGANIC LETTERS
Volume 13, Issue 23, Pages 6156-6159Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202456d
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- NASA [NNH08AI88I]
- LANL LDRD
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Visible-light-absorbing tris(bipyridyl)ruthenium(II) has been used to mediate electron transfer to N-methylpicolinium carbamates that undergo C-O bond fragmentation followed by spontaneous carbon dioxide release to give free amines. Release of several aliphatic and aromatic primary amines has been demonstrated under mild conditions using visible light.
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