Journal
ORGANIC LETTERS
Volume 13, Issue 9, Pages 2314-2317Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200566s
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Funding
- Shanghai Municipal Committee of Science and Technology [08dj1400100-2]
- Robert A. Welch Foundation [D-1361]
- National Basic Research Program of China (973) [2010CB833302]
- National Natural Science Foundation of China [20928001, 21072206, 20472096, 20872162, 20672127, 20821002, 20732008]
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A catalytic asymmetric addition of arylboronic acids to isatins has been achieved by using chiral cationic C-2-symmetric N-heterocyclic carbene (NHC) Pd2+ cliaqua complexes as the catalysts. The reaction can be performed under convenient conditions to give the corresponding adducts in good to high yields (79-94%) and moderate to excellent enantioselectivities (up to 94% ee) in the presence of LiOAr as the promoter which was generated in situ.
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