4.8 Article

An Unusual Addition Reaction for Constructing a Novel pH-Controlled Fluorescence Switch

Journal

ORGANIC LETTERS
Volume 13, Issue 2, Pages 292-295

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol102742f

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Funding

  1. National Nature Science Foundation of China [20721061, 20971127]
  2. NSFC-DFG [TRR 61]
  3. National Basic Research 973 Program of China

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A pH-controlled fluorescence switch based on a core-substituted naphthalenediimide compound (NDI-DBU) was constructed. The novel pentacyclic compound (NDI-DBU) was derived from naphthalenediimide (NDI) and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in only one synthetic operation, catalysized by CuI.

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