Journal
ORGANIC LETTERS
Volume 13, Issue 10, Pages 2524-2527Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200360f
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Funding
- Presidium of RAS [7.5, 93, 5.9.1]
- President of the Russian Federation [NSh-3230.2010.3]
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A general efficient route to hitherto inaccessible symmetric and asymmetric meso-CF3-BODIPY dyes has been developed. The key stages Include the reduction of available 2-trifluoroacetylpyrroles to the corresponding alcohols which are further condensed with pyrroles. The method allows the BODIPY with 3(5)aryl(hetaryl) and 3,5-diaryl(hetaryl) substituents to be readily assembled. The BODIPY dyes synthesized fluoresce (Phi(f) = 0.56-1.00) in the 560-680 nm region.
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