Journal
ORGANIC LETTERS
Volume 13, Issue 22, Pages 5998-6001Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2024357
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Funding
- MEXT [22000008, 23750100]
- Global COE Program for Chemistry Innovation
- Japan Society for the Promotion of Science [21.8591]
- Grants-in-Aid for Scientific Research [22000008, 09J08591, 23750100] Funding Source: KAKEN
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The reaction of a primary zinc amide with a diorganozinc reagent gives a secondary amine in the presence of Fe(acac)(3) as a catalyst and 1,2-dichloroisobutane (DCIB) as an oxidant. Halogen groups such as F, Cl, Br, and I are tolerated well. The dichloride oxidant and heat are essential to achieve the C-N bond formation presumably from a catalytic iron intermediate species bearing aryl and amido groups.
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