4.8 Article

Walsucochinoids A and B: New Rearranged Limonoids from Walsura cochinchinensis

Journal

ORGANIC LETTERS
Volume 14, Issue 2, Pages 486-489

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol203082c

Keywords

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Funding

  1. National Natural Science Foundation [81021062, 20932007]
  2. National Science & Technology Major Project Key New Drug Creation and Manufacturing program of the People's Republic of China [2011ZX09307-002-03]

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Walsucochinoids A (1) and B (2), two rearranged limonoids possessing an unprecedented carbon framework, were isolated from Walsura cochinchinensis. Their configurations were assigned as 1S, 3R, 4R, 5R, 6R, 7S, 8R, 9R, and 10R on the basis of a detailed examination of spectroscopic data, single crystal X-ray diffraction analysis, and CD experiments.

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