Journal
ORGANIC LETTERS
Volume 13, Issue 15, Pages 4068-4071Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol201571u
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Funding
- RIKEN Advanced Science Institute
- JSPS/MEXT, Japan [22681016, 23700565]
- Grants-in-Aid for Scientific Research [23700565, 22681016] Funding Source: KAKEN
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A variety of 3,4-ethylenedioxythiophene (EDOT)-based pi-conjugated molecules were efficiently synthesized in good yields through Pd-catalyzed direct C-H bond arylations, wherein a detailed synthetic investigation, including the screening of various kinds of palladium catalysts, ligands, additives, and solvents, was carried out. In addition, the spectroscopic and electrochemical properties of these EDOT-containing molecules were also investigated.
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