4.8 Article

2,5,8,11-Tetraboronic Ester Perylenediimides: A Next Generation Building Block for Dye-Stuff Synthesis

Journal

ORGANIC LETTERS
Volume 13, Issue 12, Pages 3012-3015

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol2008457

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Funding

  1. DFG [SPP1-355]
  2. One-P large-scale project [212311]
  3. BASF SE
  4. IMPRS

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Via an unprecedentedly reported ruthenium catalyzed reaction, an efficient and straightforward method was developed for the synthesis of 2,5,8,11-tetraboronate perylenediimide derivatives. A possible reaction mechanism is proposed. The synthesis of 2,5,8,11-tetra-lodo and totra-amino perylenedilmides derivatives is also reported.

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