Journal
ORGANIC LETTERS
Volume 13, Issue 22, Pages 5980-5983Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202420j
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Funding
- National Natural Science Foundation of China [21032007, 21172038]
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A palladium-catalyzed carbonylative reaction of 1-(2,2-dibromovinyl)-2-alkenylbenzene and carbon monoxide, with phenol or alcohol, is reported, which affords 1-methylene-1H-indene-2-carboxylates in moderate to good yields. This cascade process, which includes carbonylation and Heck reaction, proceeds smoothly with good functional group tolerance and high selectivity.
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