Journal
ORGANIC LETTERS
Volume 13, Issue 21, Pages 5782-5783Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202349g
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Funding
- National Basic Research Program of China (973 Program) [2010CB833200]
- NSFC [21172100, 20625204]
- MOE
- Ministry of Science and Technology [2009ZX09501-018]
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The first total synthesis of (+/-)-subincanadine C has been accomplished in a protecting-group-free fashion. This pentacyclic indole alkaloid was synthesized in six steps from the known intermediate 4, featuring Ni(COD)(2)-mediated intramolecular Michael addition as a key transformation.
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