Journal
ORGANIC LETTERS
Volume 13, Issue 6, Pages 1544-1547Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200242u
Keywords
-
Categories
Funding
- MEXT [2105]
- Meiji Seika Kaisha. Ltd.
- Grants-in-Aid for Scientific Research [21106001, 21750039] Funding Source: KAKEN
Ask authors/readers for more resources
Glycosyl sulfonium ions, which serve as persistent glycosyl cation equivalents, were prepared by the addition of diorganosulfides to an electrochemically generated glycosyl triflate. Low-temperature and variable-temperature NMR studies were performed to reveal the structure, stability, and reactivity of glycosyl sulfonium ions. The glycosyl sulfonium ions could be used as storable intermediates for reactions with various glycosyl acceptors including thioglycosides to give the corresponding disaccharides.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available