4.8 Article

Anthraceno-Perylene Bisimides: The Precursor of a New Acene

Journal

ORGANIC LETTERS
Volume 13, Issue 20, Pages 5692-5695

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol202417u

Keywords

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Funding

  1. National Nature Science Foundation of China [21031006, 20971127, 90922017, 20831160507]
  2. NSFC-DFG [TRR 61]
  3. National Basic Research 973 Program of China

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A controlled synthesis strategy for a anthracene-fused perylene bisimide was developed from the cyclization of an anthracene unit pendant to a perylene diimide scaffold. The direct cyclization led to a zigzag molecule, while a Diels-Alder strategy influenced the reglochemistry of cyclization to afford the linear precursor of a new acene.

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