Journal
ORGANIC LETTERS
Volume 13, Issue 8, Pages 2030-2033Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200417p
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- Sanofi-Aventis
- IUF
- Ministere de la recherche
- CNRS
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Bimolecular cobalt-catalyzed [2 + 2 + 2] cycloadditions between yne-ynamides and nitriles afford bicyclic 3- or 4-aminopyridines in up to 100% yield. The high regioselectivity observed depends on the substitution pattern at the starting ynamide. Aminopyridines bearing TMS and Ts groups are efficiently deprotected in an orthogonal fashion.
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