Journal
ORGANIC LETTERS
Volume 13, Issue 13, Pages 3304-3307Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200354t
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Funding
- McMaster Endowment
- Center for Photochemical Sciences from BGSU
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The synthesis of dipolar dibenz[a,c]phenazine (DBP) derivatives is described. The compounds possess little electronic communication between donor and acceptor units in the ground state regardless of the pattern of substitution. The dipolar derivatives deactivate mostly via electron transfer (eT) under polar conditions. Intersystem crossing is likely to compete for S(1) relaxation.
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