Journal
ORGANIC LETTERS
Volume 13, Issue 23, Pages 6200-6203Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202624f
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Funding
- NSFC [20962023, 21162034]
- Program for New Century Excellent Talents in University [NCET-10-0907]
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Biologically important and synthetically challenging spirocyclopentaneoxindoles with four contiguous stereocenters including one spiroquaternary stereocenter have been constructed In good yields (72-87%) with excellent dlastereoselectIvity (16:1-30:1 dr) and enantloselectivity (93 -> 99% ee) by a combined Ru-catalyzed cross-metathesis/organocatalyzed asymmetric double-Michael addition sequence.
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