4.8 Article

An Improved Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides

Journal

ORGANIC LETTERS
Volume 13, Issue 18, Pages 4974-4976

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol202098h

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Funding

  1. National Institutes of Health (NIH) [GM-46059, GM 1S10RR13886-01]

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A facile Pd-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) is described. This method allows convenient access to a variety of aryl, heteroaryl, and vinyl halides in good to excellent yields and with greatly simplified conditions relative to our previous report.

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