4.8 Article

Total Syntheses of Tardioxopiperazine A, Isoechinulin A, and Variecolorin C

Journal

ORGANIC LETTERS
Volume 13, Issue 9, Pages 2302-2305

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol2005616

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Funding

  1. NSFC [21072086, 20872054, 20732002]

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First total syntheses of the isoechinulin-type alkaloids: Tardioxopiperazine A, Isoechinulin A, and Variecolorin C have been achieved from a common key intermediate 5, which was derived from a regiocontrolled Stille cross-coupling reaction of an allylindium reagent.

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