Journal
ORGANIC LETTERS
Volume 13, Issue 9, Pages 2488-2491Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2007378
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Funding
- National Science Foundation [CHE0834862, CHE-0722319]
- Murdock Charitable Trust [2005265]
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A new C(2) symmetric salen scaffold based on cis-2,5-diaminobicyclo[2.2.2]octane has been synthesized that forms complexes with a wide range of metals. The chromium(III) complex is shown to catalyze the hetero-Diels-Alder reaction and the Nozaki-Hiyama-Kishi reaction with high efficiency and excellent stereoselectivity.
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