Journal
ORGANIC LETTERS
Volume 13, Issue 21, Pages 5808-5811Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2023856
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- Dalian Institute of Chemical Physics, Chinese Academy of Sciences
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Rhodium(III)-catalyzed oxidative olefination of N-(1-naphthyl)sulfonamides has been achieved at the peri position. Three categories of olefins have been successfully applied. Activated olefins reacted to afford five-membered azacycles as a result of oxidative olefination-hydroamination. Unactivated olefins reacted to give the olefination product. 2-fold oxidative C-C and C-N coupling was achieved for allylbenzenes.
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