Journal
ORGANIC LETTERS
Volume 13, Issue 20, Pages 5532-5535Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2022627
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- Israel Ministry of Science and Technology
- Marian Gertner Institute for Medical Nanosystems
- Tel Aviv University
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The development of a new platform for the direct and selective detection of nitrates Is described. Two thioether-based chemosensors and the corresponding sulfoxides and sulfones were prepared, and their photophysical properties were evaluated. Upon selective sulfoxidation of these thioethers with nitrates via an oxygen-transfer reaction promoted by a bioinspired Mo-Cu system, significant fluorescence shifts were measured. A selective response of these systems, discriminating between nitrate salts and H2O2, was also shown.
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