4.8 Article

Air- and Moisture-Stable p-Monothiobenzoquinones Incorporated in an Octaalkyl-s-hydrindacene Skeleton

Journal

ORGANIC LETTERS
Volume 13, Issue 10, Pages 2666-2669

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol200768b

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Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology of Japan [19002008]
  2. Grants-in-Aid for Scientific Research [19002008] Funding Source: KAKEN

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p-Monothiobenzoquinones incorporated in a fused-ring octaalkyl-s-hydrindacene skeleton have been synthesized as air- and moisture-stable reddish orange, crystals by the oxidation of mercaptophenol derivatives with DDQ, which have been characterized by X-ray crystallography to show a planar quinoid framework.

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